ࡱ> gifO h]bjbjee 4bee)\ \ 9<0uuuuuPPP///////$-350Q#PP##0uu_0&&&#^uu/&#/&&V.@.up\%#$FB. /u000N.x6i$6..n64/PJ &j PPP00{%PPP0####6PPPPPPPPP\ g: Mark Anthony Whitener DepartmentofChemistry & Biochemistry Montclair State Univresity UpperMontclair,NJ07043 e-mail:whitenerm@mail.montclair.edu www: :https://msuweb.montclair.edu/~whitener/cancer cell: by request Date of Birth August 3, 1960 LittleRock,Arkansas Education 1982-1989 HarvardUniversity Cambridge,MA Ph.D.July1990. ProfessorRichardH.Holm, Research Advisor. Thesis Title: "I. Cyclic Iron-Halide-Thiolate Clusters, [Fe3(SR)3X6]3-, Synthesis, Structure, and Solution Behavior. II. Synthesis of a Macrocyclic Trithiol as a Ligand for Biologically Relevant Iron-Sulfur Clusters." 1978-1982 SouthernMethodistUniversity Dallas,TX B.S.Chemistry,B.S.Mathematics, June1982. Professional Experience 1998-present AssociateProfessorofChemistry MontclairStateUniversity Reasearch on models of hydrogen bonding in metal bound imidazole ligands in proteins. X-ray crystallography, and coordination compounds with hydrogen bonded ligands. Preparation of metal based quasiracemates. 1993-1998 AssisstantProfessorofChemistry MontclairStateUniversity Reasearch on models of hydrogen bonding in metal bound imidazole ligands in proteins. X-ray crystallography, and coordination compounds with hydrogen bonded ligands. 1991-1993 PostdoctoralFellow UniversityofMinnesota Professor Margaret C. Etter*, Research Advisor. Studies of hydrogen bonding in solid state organic compounds. Solid state models of the interaction of hormones, drugs and neurotransmitters with their receptors. 1990 PostdoctoralFellow NorthwesternUniversity Professor James A. Ibers, Research Advisor. Studies of soluble transitionmetal selenides. 1982-1989 ResearchAssistant/TeachingAssistant HarvardUniversity Studies of iron-thiolate complexes in solution and solid state. Multistep synthesis of a macrocyclic trithiol. Compound characterization by NMR and single crystal X-ray diffraction. Teaching duties: General Chemistry Lab Instructor and Section Leader. Organic Chemistry Lab Instructor 1980-1982 UndergraduateResearch SouthernMethodistUniversity Professor Michael Lattman, Research Advisor. Preparation of hypervalent phosphorus-transition metal compounds. *Professor Margaret C. Etter deceased June 10, 1992 Mark Anthony Whitener Publications 1. Synthesis and Spectroscopic Study of a Transition Metal-Substituted Phosphorane: 2-Pentacarbonyl-manganese-2,2'-Spirobi(1, 3, 2-Benzodioxaphosphole), Lattman, M.;* Anand, B. N.; Garrett, D. G.; Whitener, M. A. Inorg. Chim. Acta 1983, 76, L139-L140. 2. A New Inorganic Ring System: Planar Fe3(m2-SR)3 in [Fe3(SR)3X6]3-, Synthesis, Structure, and Solutiion Conformation and Equilibrium , Whitener, M. A.; Bashkin, J.K.; Hagen, K. S.; Girerd, J.-J.; Gamp, E.; Edelstein, N.; Holm, R. H*. J. Amer. Chem. Soc. 1986, 108, 5607-5620. 3.  Alternative Spin States in Synthetic Analogues of Biological Clusters: Spin-Quartet Ground States and Structures of [Fe4S4(SPh)4]3- and [Fe4Se4(SPh)4]3- as their Tetramethylammonium Salts, Carney, M. J.; Papaefthymiou, G. C.; Whitener, M. A.; Spartalian, K.; Frankel, R. B.; Holm, R. H.* Inorg. Chem. 1988, 27, 346-352. 4. Oxomolybdenum (IV, V, VI) Complexes: Structures, Reactivities, and Criteria of Detection of Binuclear (m-oxo)Molybdenum(V) Products in Oxygen Atom Transfer Reactions , Craig, J. A.; Harlan, E. W.; Snyder, B. S.; Whitener, M. A.; Holm, R. H*. Inorg. Chem. 1989, 28, 2082-2091. 5.  Subsite-Differentiated Analogues of Biological [4Fe-4S] Clusters Effected by Binding of a Macrocyclic Polyether Trithiol, Whitener, M. A.; Peng, Gang; Holm, R. H.* Inorg. Chem. 1991, 30, 2411-2417. 6. N-(9-Anthracenylmethyl)-N-(2-pyridinylmethyl)-2-pyridinemethanamine, de Silva, S. A.; Whitener, M. A.;* Baron, D. E.; Zavaleta, A.; Isidor, E. V.; Allam, O. Acta Crystallographica C. 1998, C54, 1117-1119. 7. 3-[[(2-Aminoethyl)imino]methyl]-4-hydroxybenzoic Acid 0.28 Hydrate, Whitener, M. A.;* Bolt de Freitas, C.; Zavaleta, A. Acta Crystallographica C. 1998, C54, 1119-1121. 8. Quantitative Stereochemical Analysis of Reagent That Exhibits Asymmetric Amplification, B-Chlorodiisopinocampheylborane (Dip-Cl), Moeder, C. W.;* Whitener, M. A.; and Sowa, J. R. Jr.* Journal of the American Chemical Society; 2000, 122, 7218-7225. 9. Synthesis of Verbenindenes: A New Class of Chiral Indenyl Ligands Derived from Verbenone, Moeder, C. W.;* Whitener, M. A.; and Sowa, J. R. Jr.* Organometallics; 2002; 21, 144-149. 10 Study of a Fluorescent Photoinduced Electron Transfer (PET) Sensor, de Silva, S.; Kasner, M.;* Whitener, M. A.; Pathirana, S. International Journal of Quantum Chemistry; 2004; 100, 753-757. Grants Funded Transition Metal Imidazole Complexes with Carboxylate Counter Ions Petroleum Research Fund, American Chemical Society, PRF grant number 32760-B4, Mark A. Whitener, $25,000, January 1998-August 2000. Molecular Shape Directed Crystalline Architectures Peroleum Resrearch Fund, American Chemical Society, Summer Research Fellowship, Supplement to grant number 41155-B10,4, Kraig A. Wheeler (Delaware State U.) and Mark A. Whitener, $8,000, June-August 2005. Mark Anthony Whitener Presentations (presenter is underlined) 1. "Hydrogen Bonds as Design Elements in Organic Chemistry : Applications to the Preparation of Acentric Materials for Nonlinear Optics", Whitener, M. A.; Etter, Adsmond, D. A.; Cicero, A.; Frankenbach, G. M.; Huang, K.-S.; MacDonald, J. C.; Reuss, V. A.; and Videnova-Adrabinska, V. American Crystallographic Association Annual Meeting, Pittsburgh, PA; August 9-14, 1992. Invited Talk. 2. "Crystal Structures of Ammonium and Ethanolammonium Salts of Carboxylic Acids as Models of the Interactions of Hormones, Neurotransmitters and Drugs with Their Receptors", Whitener, M. A.; Etter, M. C. American Crystallographic Association Annual Meeting, Pittsburgh, PA; August 9-14, 1992. Poster Presentation 3. Crystal Structures of Ammonium and Ethanolammonium Salts of Carboxylic Acids as Models of the Interactions of Hormones, Neurotransmitters and Drugs with Their Receptors, Whitener, M. A.; Etter, M. C. 4th Midwest Organic Solid-State Chemistr Symposium, University of Nebraska, Lincoln, NE, June 19-20, 1992. Invited Talk. 4. Synthesis and Crystallographic Characterization of 2-Trifluoromethylindinium(1,5-Cyclooctadiene), Albietz, P. J. Jr.; Whitener, M. A.; Sowa, J. R. Jr. 211th American Chemical Society National Meeting, New Orleans, LA, March 24-28, 1996, INOR # 120. Poster Presentation. 5. Synthesis and Crystallographic Characterization of 2-Trifluoromethylindenyliridium(1,5-cyclooctadiene), P. J. Albietz, Jr., and co-authors: J. R. Sowa, Jr., M. Whitener, 1996 Rutgers Research and Careers Symposium, Rutgers University, Piscataway, NJ, April 19, 1996. Poster Presenttion 6. Synthesis and Crystallographic Characterization of 2-Trifluoromethylindenyliridium(1,5-cyclooctadiene), P. J. Albietz, Jr., and co-authors: J. R. Sowa, Jr., M. Whitener, 41st Annual Meeting of the New Jersey Academy of Sciences, Seton Hall University, South Orange, NJ, May 11, 1996. Poster Presenttion 7. Polyimidazole Transition Metal Carboxylates: Models for Hydrogen Bonding of Metal Bound Histidines in Proteins, Whitener, M. A.; Bolt de Freitas, C.; Kuar, G.; Lieu, D.; Marchesano, N.; Ordaya, L.; Rosko, J.; Vassiliou, E.; Victorin., S. American Crystallographic Association Annual Meeting, St. Louis, MO; August 9-14, 1997. Poster Presentation. 8. Routine and Unusual Structures of Copper-Imidazole Complexes with Carboxylate Counter Ions, Whitener, M. A.; Roy, M.; Victorin, S.; Kasner, J.226th American Chemical Society National Meeting. September, New York, September 2003.Poster Presentation. 9. Structural and Computational Studies of Fluorescent Photoinduced Electron Transfer (PET) Sensors for Cations, de Silva, S. A.; Whitener, M. A.; Kasner, M. L.; Pathirana, S. L. 226th American Chemical Society National Meeting. September 2003, New York. Poster Presentation. 10. PolyimidazoleTransition Metal Carboxylates as Models of Hyrogen Bonding in Proteins, Whitener, M. A.;. Deleware State University Chemistry Department Seminar; Dover, DE; October 31, 2003. Invited Talk. 11. Computational Study of a Fluorescent Photoinduced Electron Transfer (PET) Sensor for Cations, de Silva, S. A.; Kasner, M. L.; Whitener, M. A.; Pathirana, S. L. 12th Conference on Current Trends in Computational Chemistry. October 2003, Jackson MS. Invited Talk. 12. Routine and Unusual Structures of Copper-Imidazole Complexes with Carboxylate Counter Ions, Whitener, M. A.; Roy, M.; Victorin, S.; Kasner, J.American Crystallographic Association Annual Meeting, Chicago, IL; July 17-22, 2004. Invited Talk. 13. Synthesis and Crystal Structures of Five bis(3-X-N-Phthaloylalaninato)bis(N-Methylimidazole)Copper(II) Complexes (X = -H. -NO2, -Cl, or -CH3). Approaches to Metal Based Quasiracemates, Whitener, M. A.; Patel, H.: Singhal, M. American Crystallographic Association Annual Meeting, Chicago, IL; July 28-August 1, 2012. Contributed Talk. 14. Preparation and Crystal Structures of Quasiracemate Bis(N-Methylimidazole)Copper(II) Complexes with Substituted N-Phthaloylalaninato ligands Whitener, M. A.; Ahmad, R.; Khusboo Hussain, K.; Patel, H.: Singhal, M. Gordon Reseaarch Conference: Crystal Engineering, Waterville Valley, NH Summer 2018. Poster Presentation. 15. Doing Structural Coordination Chemistry Reserch with Limited Funds Whitener, M. 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